Spectral Data • Summer 2009
Below
are links to the 1H-NMR spectra–in pdf
format–collected during the four projects. Each
student is responsible for downloading, printing
and analyzing their NMR spectra. Be sure to include
this data in your lab reports. Also, bring a copy
of all your data to class to discuss.
If you would like your spectra reprocessed (i.e. with better peak picking or integration), email Chad with your request.
If you would like to obtain a spectra of a new sample, prepare the sample and give it to your TA.
The filenames follow the general format:
If you would like your spectra reprocessed (i.e. with better peak picking or integration), email Chad with your request.
If you would like to obtain a spectra of a new sample, prepare the sample and give it to your TA.
The filenames follow the general format:
Starting Materials
Below are links to several starting materials used in each of the four projects. Compare the signals in these starting materials to those in your product. Which signals would you not expect to see in the product? What new signals would you expect to see? Which would you expect to be at similar positions (chemical shifts)? The 1H-NMR spectra of some solvents and reagents encountered in your syntheses have also been included since these appear to be common impurities present in several of your spectra.
If there is a starting material, reagent or solvent you'd like to see on this list, please prepare a sample and give it to your TA.
Below are links to several starting materials used in each of the four projects. Compare the signals in these starting materials to those in your product. Which signals would you not expect to see in the product? What new signals would you expect to see? Which would you expect to be at similar positions (chemical shifts)? The 1H-NMR spectra of some solvents and reagents encountered in your syntheses have also been included since these appear to be common impurities present in several of your spectra.
If there is a starting material, reagent or solvent you'd like to see on this list, please prepare a sample and give it to your TA.
Project 2: Benzanilides; Hammett Plot
Project One: Nuc. Acyl Substitution
hexynol
ethanol
ethanol
diethyl
ether
octynoate
octynoate
Project 4: CASPiE: Anti-Viral
Triazoles
Project 3: [R] Amination;
Hydrogenation
anum_amine.pdf
anum_imine.pdf
anum_imine_postTES.pdf
anum_amine_postTES.pdf
scavone_amine.pdf
scavone_imine.pdf
scavone_imine_postTES.pdf
scavone_amine_postTES.pdf
pham_imine.pdf
pham_amine.pdf
pham_imine_postTES.pdf
pham_amine_postTES.pdf
Some of the spectra above were reprocessed so that signals could be more clearly identified and so that J-values could be calculated. These reprocessed spectra are below.
anum_amine.pdf
anum_imine.pdf
anum_amine_postTES.pdf
tony_amine.pdf
tony_imine.pdf
tony_amine_postTES.pdf
francis_imine.pdf
anum_imine.pdf
anum_imine_postTES.pdf
anum_amine_postTES.pdf
scavone_amine.pdf
scavone_imine.pdf
scavone_imine_postTES.pdf
scavone_amine_postTES.pdf
pham_imine.pdf
pham_amine.pdf
pham_imine_postTES.pdf
pham_amine_postTES.pdf
Some of the spectra above were reprocessed so that signals could be more clearly identified and so that J-values could be calculated. These reprocessed spectra are below.
anum_amine.pdf
anum_imine.pdf
anum_amine_postTES.pdf
tony_amine.pdf
tony_imine.pdf
tony_amine_postTES.pdf
francis_imine.pdf
Triazoles & Intermediates (GC-MS)
The first file below contains the structures, molecular formulas and masses of the target compounds in vials 1-8 as well as the intermediates leading to each target.
antiviral_masses.pdf
vial1_ascav_P5.pdf
vial2_ascav_P5H5.pdf
vial3_ascav_P5H8.pdf
vial4_araza_P21.pdf
vial5_araza_PhH26.pdf
vial6_araza_P21H8.pdf
vial7_fpham_P5H22.pdf
vial8_fpham_P5H0.pdf
The first file below contains the structures, molecular formulas and masses of the target compounds in vials 1-8 as well as the intermediates leading to each target.
antiviral_masses.pdf
vial1_ascav_P5.pdf
vial2_ascav_P5H5.pdf
vial3_ascav_P5H8.pdf
vial4_araza_P21.pdf
vial5_araza_PhH26.pdf
vial6_araza_P21H8.pdf
vial7_fpham_P5H22.pdf
vial8_fpham_P5H0.pdf